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[Marxism] Big Science
LRB | Vol. 28 No. 2 dated 26 January 2006 | Steven Shapin
Steven Shapin
Between Genius and Genocide: The Tragedy of Fritz Haber, Father of Chemical
Warfare by Daniel Charles [ Buy from the London Review Bookshop ] · Cape,
313 pp, £20.00
Hydrogen and nitrogen combine only with difficulty. Since the reaction N2 +
3H2 <?> 2NH3 is reversible, you need just the right conditions to drive it
forward to produce significant quantities of ammonia (NH3). If the
temperature is too low, the formation of ammonia is favoured but the
reaction goes slowly. If the temperature is too high, the reaction goes
faster, but any ammonia produced tends to dissociate into its elements.
Pressure is another relevant variable: higher than atmospheric pressures
favour ammonia formation. So, if ammonia is what you want, you need very
cleverly to manipulate temperature, pressure, a catalyst and the design of
the reaction vessel. In 1909, the academic physical chemist Fritz Haber and
the industrial metallurgical engineer Carl Bosch succeeded in doing this,
and they patented the process the following year. Within four years, the
process had become commercial, the foundation of a huge German-dominated
industry centred on ammonia works in Oppau and, from 1917, in Leuna. Haber
became famous and wealthy. The giant chemical firm Badische Anilin und
Soda-Fabrik (BASF) ? later folded into I.G. Farben ? had been funding
Haber?s research, doubling or tripling his already generous professorial
salary at Karlsruhe, on the condition that he obtain company permission
before publishing any details, and the terms of the BASF patent gave him
1.5 pfennigs for every kilo of ammonia produced using his process. In the
last year of the war, the factories in Oppau and Leuna produced 115,000
tons, and Haber?s royalty payments were worth the present-day equivalent of
about $4 million. Haber won the Nobel Prize for Chemistry in 1918; Bosch
became chairman of BASF, which made huge amounts of money from the process,
and he too eventually won the Nobel Prize (in 1931). All this represented
an early milestone in the formation of what came to be called the
military-academic-industrial complex.
Along with DNA, ammonia is a candidate for ?molecule of the 20th century?.
DNA is a very large molecule, and ammonia a very small one, but ammonia has
greater bearing on the way in which the century?s history unfolded.
Synthetic ammonia is both a foundation stock for the manufacture of such
nitrogenous fertilisers as ammonium nitrate or sulphate, and a substance
which, in its liquid state, can be directly injected into the soil. Plants
need nitrogen to grow but they cannot get it directly from the atmosphere,
which is 78 per cent nitrogen by volume. Legumes ? plants like peas, beans
and clover ? harbour nodules of nitrogen-fixing bacteria in their roots,
converting free atmospheric nitrogen into compounds usable in plant
metabolism, and you can plant legumes to give the soil a dose of fixed
nitrogen. But prior to the Haber-Bosch process, sources of
nitrogen-containing fertilisers were limited. You could use animal manure,
but that was bulky, hard to distribute and low in nitrogenous oomph. You
could use the bird fecal deposits called guano, usually obtained through a
vast global trade from islands off the coast of Peru, or the naturally
occurring nitrates from saltpetre deposits in the deserts of Chile. But by
the end of the 19th century, it was looking as if both of these sources
would soon be exhausted.
In 1898, the English chemist William Crookes sounded a Malthusian alarm:
the world?s population, he said, would very soon outstrip its food supply.
This was a global crisis in the making, but, Crookes warned, it was
especially acute for white people: ?The fixation of nitrogen,? he
announced, ?is a question of the not-far-distant future. Unless we can
class it as among certainties to come, the great Caucasian race will cease
to be foremost in the world, and will be squeezed out of existence by races
to whom wheaten bread is not the staff of life.? Crookes?s apocalyptic
vision was widely credited and may indirectly have inspired Haber?s work.
The production of cheap synthetic fertilisers permitted by the Haber-Bosch
process was a vital ingredient in the sevenfold increase in the world?s
food supply during the course of the 20th century and the almost fourfold
increase in its human population. Brot aus Luft was the slogan: bread out
of the air. A hundred million tons of nitrogen a year are now removed from
the atmosphere and turned into fertiliser. That?s the bit of Haber?s career
which gets him called a genius and a saviour of humankind.
The same synthetic ammonia that could be transformed into fertiliser could
also, by way of nitric acid, become a feedstock for military explosives.
After the outbreak of the Great War, the British blockade cut Germany off
from its Chilean nitrate supplies, and the rate at which the Haber-Bosch
process could make ammonia became crucial to Germany?s ability to wage war,
and, especially, to its strategic planning. If enough of the stuff could
not be made, a protracted war was bound to be a disaster. In the autumn of
1914 it became clear that Germany would run out of munitions in six months
if further nitrate supplies could not be secured. Haber was already on the
job, becoming head of the chemistry department of Walter Rathenau?s
Kriegsrohstoffabteilung (War Raw Materials Section). For this, and other
reasons, he became a hero of the war effort.
The most notorious of his contributions to the war ? and probably the one
which most engaged his enthusiasm ? was poison gas. That?s the bit of
Haber?s work which attracts Daniel Charles?s description of him in the
subtitle of his new biography as the ?father of chemical warfare?. As early
as December 1914, Haber attended a test-firing of munitions containing a
tear gas called xylyl bromide, and was immediately gripped by the
opportunities gas offered to the patriotic chemist. He had a better idea
than using gas to burn soldiers? eyes and put them temporarily out of
commission: he wanted, as a co-worker related, ?something that puts people
permanently out of action?. Some colleagues drew back from the idea, but
Haber suggested to the High Command using the asphyxiating gas chlorine in
the stalled trench warfare of the Western Front. The generals had
misgivings ? if the Germans could use gas, so could the British and French
and, anyway, it seemed unsporting ? but they agreed, and on 22 and 23 April
1915 several hundred tons of chlorine gas were released into trenches
around Ypres occupied by Canadian, French and Algerian soldiers: Tod aus
Luft this time. The Germans gained about a mile of territory, and fewer of
the enemy than Haber would have liked were ?put permanently out of action?
? perhaps 350 were killed and 7000 disabled. Haber was miffed that the
advantage of being the first to use poison gas was not pressed home: if the
German generals had been more serious about gas, he reckoned, the Allies
could have been driven into the sea in quick order.
full: http://www.lrb.co.uk/v28/n02/print/shap01_.html
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